I think we're confusing the odds of rolling at least one 6 with the OP. The OP gives us this one 6, we're asked the odds of the other being a 6. We only have six possible trial results; (6,1),(6,2),(6,3),(6,4),(6,5),(6,6); all other combinations are ignored.
The operative phrase in the OP is "'at least one of the dice is a 6.'", it doesn't matter which die is a 6.
