Except that axioms are provable. The proof of an axiom consists of the statement of the axiom, and commenting that it is, in fact, an axiom.
There are, however, statements which cannot be proven. Gödel famously proved that in any self-consistent system sophisticated enough to encompass arithmetic, there must exist statements which are true, and yet which cannot be proven within that system. For instance, it is possible to express in the notation of such a system a statement G equivalent to “This statement cannot be proven within this system”. If statement G is true, then by its own truth, we can deduce that G cannot be proven. If, on the other hand, G is false, then it cannot be proven by virtue of being false, since a self-consistent system cannot prove a falsehood. Therefore, either way G cannot be proven. But that’s exactly what G is saying: G says that it can’t be proven, and in fact, it can’t be. So G is true. Ergo, there exists at least one statement in any given system which is true, but which cannot be proven in that system.
Now, that one’s a pretty pathological case, and aside from exposing a quirk of mathematics, it doesn’t really do much for us. But there are more useful examples. For instance, in geometry, exactly one of the following statements is true:
The sum of the angles of a triangle is exactly 180 degrees
The sum of the angles of a triangle is less than 180 degrees
The sum of the angles of a triangle is greater than 180 degrees
One of those three must be true, and the other two must be false. Which one’s the true one? There’s no mathematical way to know. Unless you take one of those statements, or its equivalent, as an axiom, you can’t prove it. You can, however, answer the question scientifically (or at least attempt to do so), by measuring the angles of real triangles.