That bit in Yojimbo where Mifune is sitting in the bell tower and watching the two gangs try to work thier way up to actually fighting each other. Most of the rest of the film had the typical for the time overbearing score, but for that bit it worked great.
And the cheesy but fun movie Demon Knight had a scene where the Billy Zane (as the devil, of course) is trying to tempt the cute work-release girl, which had GREAT music. Sort of a light hip-hop thing, which normally I don’t like, but for that scene it was great. Which is odd, considering it’s not “scoring” in the usual sense, it’s just a clip from a song with the words taken out.
And while it was not, technically speaking, a movie, the end movie for Fallout, with the battered Vault Dweller limping off into the endless wasteland to the Inkspots’ “Maybe” is branded forever into my mind. Especially considering they used the same song for the opening, which had a totally different feel.
Planescape: Torment almost (but not quite) bested this in a couple of places, the start and end movies were likewise incredible, and there was a bit near the start where you run into the ghost of The Nameless One’s “lover” was unbelivable, especially considering it’s almost all done in text . . .
For TV shows, the last few minutes of Za’Ha Dum, the season three ending for Babylon 5 was scored amazingly well, even by the high musical standards of the rest of the show.
Anime-wise, all of Yoko Kanno’s scores are great, but she really outdid herself in a few places. That bit in Escaflowne where Van masacres the (poorly named) Dragonslayers right in front of Delandau, the flashback sequence when Spike is falling out the church window in Cowboy Bebop, and the whole last quarter of Macross Plus (from Information High onwards) In all three, the music and images just mesh perfectly . . .
Though I think the winner would have to be the scene in Perfet Blue (hey, that actually WAS a movie) where the guy gets icepicked to death to the bubbly idol music, with the quick cuts to the magazine pictures. Though there was a very similar scene in Babylon 5 that worked almost as well. (Which was based on a scene from Caberet . . .)
I wish I could find a soundtrack for Eat Man '98, perticularly the playful, vaugly gypsy-like bit in the first episode, which seemed to perfectly capture the feel for the series when mated with the bits of Bolt deliberatly getting himself arrested.
And I’m amazed this has gone on this long without someone mentioning the “Sad walking away theme” from the Hulk TV show . . . though that was really the song itself that was great, not the scoring.
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“Something that Hichcock would be proud of . . . his dog directing.”