It’s difficult to determine why some weapon became a priority and another weapon lacked support without searching the major players correspondence. If Marshall wanted more Mossies, it would have been a done deal (unless Roosevelt overruled him).
Arnold wasn’t the “head of the US Air Force” at that point in time and it appears he was lucky just to be promoted to major general.
The disfavor shown Arnold by Roosevelt reached a turning point in March 1941 when new Secretary of War Henry L. Stimson, a supporter of Arnold, submitted his name with two others for promotion to the permanent rank of major general.[nb 30] Roosevelt refused to send the list to the Senate for confirmation because of Arnold’s nomination, and his forced retirement from the service seemed imminent to both Stimson and Marshall. Stimson and Harry Hopkins arranged for Arnold, accompanied by Maj. Elwood “Pete” Quesada, to travel to England for three weeks in April to evaluate British aircraft production needs and to provide an up-to-date strategic analysis.[93][nb 31] His meeting with Roosevelt to report his findings was judged as impressively cogent and optimistic, but the president ruminated on Arnold’s future for three weeks before submitting his name and the others to the Senate. From that point on, however, Arnold’s “position in the White House was secure.”[94][nb 32] His importance to Roosevelt in setting an airpower agenda was demonstrated when Arnold was invited to the Atlantic Conference in Newfoundland in August, the first of seven such summits that he, not Morgenthau, would attend.
I’m under the impression that every commander wanted “more” of something. More tanks, more M1 garands, more B29s, more men, more food, more bullets, etc. Every one of them had to make a case as for why they needed it. Sometimes, there just wasn’t enough money to get the job done or there was another weapon in the works that could do the same job and maybe do it better.
While the Mossie did well against some targets and was the only choice for others, it wasn’t considered the first choice for most missions. Just for comparison purposes, how many Mossies and how many sorties would it take to knock out the heavily defended Schweinfurt-Regensburg ball bearing factories in 1943?
