Generally speaking (within science at least), your definition of a dimension fits. However, as I understand it, string theory and such require 10 time-space dimensions, which temperature does not qualify as.
As for the definition of a point with x,y,z,t,T… well, a point doesn’t have a T. T is average kinetic energy. That point has KE, but it doesn’t have T.
That aside, though, you can’t define two separate objects with the same x,y,z,t and different T’s–for example, if one ball is at 1,1,1,1,1, the second ball CAN’T also be at 1,1,1,1, and simply have a different T (3 balls in a box each have a different x,y,z at given time t; to count as a fifth time-space dimension, they’d need to be able to have the same x,y,z,t, but a different coordinate w that uniquely defines them).
Note I also realize that x,y,z aren’t hard-set as the 3d space dimensions (a simple example being spherical coordinates, which can also be used to define the same point)… perhaps if I sit and ponder how x,y,z and r, theta, tau (or whatever it is you use for spherical coordinates, it’s been a long time) can be the same thing for long enough I can grok a fifth coordinate in a “spherical” system