In that case my suggestions in post #47 are reasonably close by. Also, I don’t know why I didn’t mention the Pana’ewa Zoo, which is no great shakes compared to world-class zoo facilities but is an extremely pleasant place to stroll through. They have two new tigers, too, one white and one orange, to replace the beloved Namaste, their white tiger who finally died of old age.
I agree with Moonlitherial that Hawaii Volcanoes National Park will be a significant part of your visit. At the moment (as it has been for several years, though things could change quickly), there is great viewing of lava flowing into the ocean, best seen at nightfall, outside the park at Kalapana. If an 8-mile-round-trip walk, or a similar distance on rented trail bikes, is out, then you’ll have to skip this one. But assuming you don’t mind a little exertion (and it’s not hard; the going is pretty flat), this is a memorable sight.
South of Volcano, you may want to check out Punalu’u Beach, a particularly beautiful black sand beach (and a nice place to picnic). You could do that on the way to or from South Point (a longish but beautiful drive from Volcano). However, the best thing to do at South Point is to visit Green Sands Beach, and unless you’re a local with a 4WD vehicle, that means another walk. As is usually the case on the Big Island, it is abso-fucking-lutely gorgeous, but if even a modest hike is out of the question, it won’t work.
One site I probably recommend skipping is the Mauna Loa factory tour (it’s sort of across the street from the zoo). We went there years ago, thinking that even if the tour of the factory was not a big thrill, we’d be able to buy macadamia nuts more cheaply there. Nope. The nuts are just as expensive as in the grocery store. And the factory is only in operation for a couple of months a year, so the rest of the time there is just this lame video of “how nuts are harvested,” reminiscent of what a substitute 5th grade teacher would have had you watch in 1974.
I say “probably” skip the factory because I think it actually does process nuts in October, and IIRC it’s free. So if you are in the area already with some spare time, you could check it out just for shit 'n giggles. (If it’s awesome, let me know so I can update myself.)
Unfortunately I think Moonlitherial may be wrong about there being a Hilo-side pick-up for the Mauna Kea tour, but don’t take my word for it; I hope I am wrong. Just be aware that there may not be. It will make for a REALLY long day if you have to go from the Hilo side over to Queen’s Market in Waikoloa (where I know there is a pick-up), take the tour, and then drive back to Hilo-side late at night.
I’ll post again later if I think of more stuff.