That’s true - in rocks, paper, and scissors. It’s not true in poker.
Here’s an example. You’re playing poker against Robbie the Robot. Robbie has been programmed to know all the probabilities. But he has not been programmed to practice any form of deceit. He will always play strictly by the numbers. He will only bet if he calculates the odds are in his favor.
You have a hand with four queens. They’re visible on the table so Robbie knows you have four queens.
Robbie’s visible hand is three kings. He also has a hole card which you can’t see. But you know that your hand will beat any hand Robbie can have unless his hole card is the fourth king. And you know the odds of that are slim. So you play the odds and raise, in expectation that Robbie will fold.
But then Robbie doesn’t fall. He calls and raises. What do you do now? Remember, Robbie only plays the probabilities. He can see that you have four queens. And he can see his hole card, which you cannot. And he is raising so he must be calculating that the odds favor his winning the hand.
At this point, what are you going to conclude Robbie’s hold card is? And based on that conclusion, are you going to call or fold?
This demonstrates how rational play works. Now here’s how irrational play works.
Robbie had a short circuit. His hole card is a four. His hand is three kings and he can see your hand is four queens. There is no rational way that Robbie can expect to win this hand. But the short circuit has damaged his brain and is making him do the opposite of what he should do. He is acting irrationally and is betting more money on a hand he knows he has no chance of winning.
But as pointed out above, you are expecting Robbie to be rational so you fold. Robbie just won money by acting irrationally that he would have lost if he had been acting rationally. Irrational play can beat rational play.
You might argue that we don’t play poker with robots. We play poker with human beings and we expect the possibility of irrational play. And you’re right.
But if your claim was correct - that “irrational play can never beat rational play” - then we wouldn’t expect irrational play. We would always use rational play if it always beat irrational play. The reason we expect the possibility of irrational play is because it does sometimes get used. And the reason it sometimes gets used is because sometimes it beats rational play.
Three kings and a four cannot beat four queens in a rational play. But three kings and a four can beat four queens in an irrational play.