In any finite period of time, of course there is luck involved in poker. The best players in the world can and do get beaten up badly on occasion by rubes who happen to hit an unbelievably lucky string of cards. Talk to any professional player, and they’ll be able to tell you about bad luck streaks that hurt them and cause them to lose money for weeks and sometimes months on end. As the number of hands played goes up, eventually skill comes to dominate luck. But in the short run, luck is a dominating factor.
This is less true in shorthanded games and no limit poker. In a limit game with 10 players, luck is a big part of your results in a given night.
As for mathematicians playing poker, sure there are lots of them. Almost all the really good players I know have strong math backgrounds. One’s a computer scientist with a masters. Another has a degree in math. A third is an accountant. But being able to do math isn’t necessary to play the game. I don’t calculate pot odds while I’m playing except in rare circumstances.
Where math knowledge helps is in being able to see the big picture, to maintain that detached, critical frame of mind that allows you to look past the streaks and the luck and make the right plays over and over again. Players with weak understanding of math often make mistakes like chasing streaks, changing strategy because the right one isn’t ‘lucky’ for them, etc. You hear a lot of weak players saying stupid things like, “I’d rather have TJs than AA. I always lose with aces.” You’ll never hear a player who understands the math behind the game say that.
Mathematical knowledge is necessary to analyze the game and determine the correct strategy. If you’re writing a book on how to play poker, I hope you understand game theory, statistics, logic, and a host of other mathematical disciplines that help you determine what is and isn’t correct strategy. But when it comes to playing, you just need to be able to grasp the concepts that other people have figured out and apply them.
Sometimes too much focus on the math is a bad thing. I’ve seen players waste their mental effort in trying to determine exactly how many chips are in the pot so they can calculate whether they should call a certain sized bet with their drawing hand - and while being so distracted not noticing that the guy who bet probably doesn’t even have a real hand, or that the guy behind is already reaching for his chips to raise. Trying to do pot odds math at the margin is a waste of time, and your effort is much better expended examining your opponents and recognizing patterns in their play, or being able to see that if you hit your hand the player you’re up against is likely to pay you off.
Another way that overly-mathematical players can go wrong is that they treat the game mechanically. I’ve known players who bring books to the table and read while playing, and only look up when it’s their turn to act. They apply the pot-odds math and call or fold. Some of these players are winning players (barely), but could win much more if they’d throw the damned book away and start paying attention. I was guilty of that a bit myself when I first started playing - I thought I was this super-smart math guy who had it all figured out. But I saw the error of my ways in a few weeks and cut it out. Some players never see it.