Arrested for being in same sex marriage? No, I don’t know of any. But even in 2013, people were being arrested for being willing to engage in consensual homosexual sex in private. Absolutely, the law was unenforceable. But arrests were still made. Could I see that being turned into “well, they have a marriage license, so that’s evidence that they are engaging in illegal sex?”
The Lovings were raided in an attempt to catch them having (illegal) sex. They were sleeping, so the illegal marriage license was the charge.
http://www.nola.com/crime/baton-rouge/index.ssf/2013/07/east_baton_rouge_sheriffs_offi_9.html