There isn’t any practical way to extinguish a lithium ion battery fire. Full stop.
There are plenty of products hitting the market (one might call them schemes or gimmicks) with the claim that it’s the Next Best Thing for battery fires. I have yet to see anything that shuts the fire off.
What’s actually happening with a battery fire isn’t that there’s a matteess-sized or shoe-box-sized battery on fire; what’s really going on is hundreds or thousands of smaller battery cells, all tucked in snuggly next to their siblings, that are on fire. Each cell looks like a big AA battery (they’re called 18650s, as they’re 18mm wide by 65mm long, but I can’t think in metric). When one cell gets upset - which could be from overcharging, from overdischarging, from an external short, an internal short (the likelihood of which gets greater over time due to dendritic somethingorother inside the cell), from overheating, or from trauma - the cell goes into what’s called thermal runaway. The cell heats up enough as all of the stored energy is converted to heat, which pressurizes the cell, bursting it and releasing the electrolyte, which is flammable. The now burning electrolyte heats up the neighboring cells, which go into runaway, rinse, lather, repeat.
The electrolyte also contains oxygen, so the fire is going to burn inside the case regardless of what we do. Cooling it down or chemically interrupting the fire are the only ways out of this mess.
The key to putting out a battery fire is stopping the progression of thermal runaway.
The problem is that the battery manufacturers are trying to maximize density, so the cells are tucked as close together as possible. There are little to no channels inside the battery case where we can put water inside to cool it down. That said, if we put water in, it shorts out other cells and now they’re in thermal runaway. Whoops.
Ok, let’s open the case up. There are piercing nozzles on the market that poke a hole into the case and spray water. Now I have trauma to cells and water. More thermal runaway cells. Whoops.
What about chemicals of some variety? It needs to be electrically inert, non corrosive, easily conveyable through a hose or extinguisher, and I need a way to inject it into the battery in a way that I can reliably get to when the battery is on fire. Let me know when someone invents one that works, I’ll buy some stock.
The current philosophy, as was stated above, is to let the battery burn itself up and protect exposures. If we attack an EV car fire the way we’ve attacked ICE fires for the last 120 years, we use 40,000 gallons of water (which gets contaminated) and it takes 8 hours. When you’re done, you have a burned up car. If we protect exposures only and let the car burn, we re done it 2 hours and have little to no contaminated water, and still end up with a burned up car.
The blankets that go over the car or the bags that you put the device in are an interesting idea, but there’s a valid concern that while you’ve covered the burning thing, the flammable electrolyte is building up under the blanket/bag. If I can confine enough of it and still have an ignition source, I can have an explosion. Not optimal.
E-mobility devices scare me to no end. I worry more about those than cars. People bring them into their homes and apartments, and leave them next to the front door. They overcharge. They beat on the batteries while they ride them. They use non-listed third party batteries. They modify the batteries to get higher discharge rates. Park them outside 10 feet away from anything you care about.
Smaller battery powered devices like phones and laptops aren’t a big deal in my mind. Sure, they can catch fire. Toss it into the oven or into the kitchen sink or the bathtub (a cast iron tub, not a fiberglass tub) and call the fire department. We in the 2020s don’t remember how many appliances caught fire in the 1960s to 1990s. We’re just back to what’s new is old again.
We figured out how 100 years ago how to handle a car with 15-25 gallons of gasoline in it. The problem we have now is that technology is outpacing our ability to write codes and standards on how society deals with the new stuff. In 10 years we’ll have this thing solved.