And two good sites from entities within the Smithsonianian:
http://www.siris.si.edu/
The Smithsonian Institution Research Information System (SIRIS). An online card catalog for all of the Smithsonian libraries. Over a million books. You can seach by title, author, subject, or keyword.
A very informative website dealing with psychoactive plants, chemicals & the issues surrounding them is The Vaults of Erowid. It’s a great source of information–good for debunking rumors, urban legends & all sorts of misconceptions regarding drugs.
Also–The Crime Library is a great resource for in-depth reporting of many infamous murders, serial killers, etc…
Rutgers University Library’s Electronic Reference Sources, including dictionaries, newspapers, mapping, just about anything. (Unfortunately some of the resources require a rutgers login, but others are free to use.)