Clarence Boddicker (Kurtwood Smith) from Robocop
He’s also a good bad guy.
Michael Wincott in pretty much everything he’s ever been cast in. (See, e.g., The Crow and Strange Days). I borrowed his voice for one of my own more villianous PCs in a CP2020 game, and was pretty decent at it.
Paul Newman in The Hudsucker Proxy. Sure, sure.
Patric Zimmerman as Revolver Ocelot in every Metal Gear Solid game other than MGS3.