You probably already know this, but that isn’t a specifically human/hominid break but one that happened more than 60 million years ago. (And there actually are hypothesii that it is an advantageous adaptation.)
Pale palms, on the other hand (okay, on both hands) is a human thing. Whyever it happened, it happened after humans split from chimps. And chimps (and gorillas) have fingerprints on their black hands.