On big airplanes the preflight is a bit different from small ones. But the concept is the same: look for the things that commonly go wrong and can be seen from where you are.
While we do have professional maintenance, they aren’t checking the airplanes before each departure. That went out 30 years ago with deregulation in the name of lower fares.
So what am I looking for on a big jet walk around?
I’m looking for tire condition & inflation. Dents from birdstrikes, or more likely, baggage loaders or catering trucks.
I’m also picking up trash on the ground so it doesn’t get embedded into a tire or sucked into an engine. Those crappy little luggage locks you’re always losing from checked baggage? Guess where a lot of them end up. It’s easy to cause $100K of damage sucking up one or two of those. Tires are anywhere from $500 to $10,000 apiece & are replaced if crap gets embedded in them or they get a cut.
At the engines I’m looking for leaks & bent or damaged blades on the intake or any unusual soot patterns or metal cracking in the tail pipe. Make sure the reversers are stowed properly.
In the landing gear wells and along the wings and tail there are a thousand places hydraulics can begin to leak. Likewise fuel tanks can leak. So any fluids or fluid stains on the skin are of interest. There’s always some, so it’s a matter of enough but not too much.
The landing gear itself has a bunch of movng parts, pivots, braces, locking jaws, etc. Those should be clean & shiny where they’re supposed to be clean & shiny and have the right amount of decently fresh grease where they’re supposed to be greasy.
Therere are often service points in the gear wells or nearby where maintenance can top off this or that fluid. In most cases there’s a small quantity or pressure gauge nearby which needs to be indicating the right values.
Some lights are left on at all times and if so the bulbs should be on, not burnt out. Even the lights which are off get a look, since a burned out bulb often looks different enough to be detected.
if it’s snowy or icy either here or where the airplane came from, we’re also looking to see where ice or compacted snow is stuck to what. Some deice fluids dry to a hard gunk and we also don’t want too much of that hanging around moving parts lest they fail to move when needed.
There are numerous intake & exhaust vents, ports, sensors and antennas scattered around the aircraft. Each gets a quick look for normalcy. Some should be open, others closed. Some have fans that should be sucking, blowing, or not. Some sensors should be shiny, others dull or greasy. Nothing should be bent or broken.
etc.
Having written all the above I found this: http://www.b737.org.uk/walkaround.htm which is a good laymen’s intro to airliner walkarounds with nice pictures. The page layout is kinda weird, you have to scroll down quite aways to see the actual content.