1. Potatoes; 2. ??? 3. Profit!--I mean vodka!

I don’t know how it is with potatoes, but with malted grain, there’s a precise band of temperatures you have to reach for the amalyze to take effect. Anything over 170 F and the enzymes (alpha- and beta-amalyse) are effectively shut off. IIRC, it’s about 158-162 F for one hour or so to effectively convert the starches in malt into fermentable sugars.

I would guess potatos would work similarly.

I meant to say 148-152 F.

There are much safer ways to distill out there that take longer but do not require excessive amounts of heat. Also, there are freeze-distillation methods not particularly great, but they do work. They are occassionally employed by homebrewers to make eisbeer, but they are technically illegal if they increase the alcohol content by something like 1/2%. I’d have to look up the exact numbers.