The powers of the President of the United States, per the Constitution of the United States, Article II:
"Section 1. The executive power shall be vested in a President of the United States of America…
"Section 2. The President shall be commander in chief of the Army and Navy of the United States, and of the militia of the several states, when called into the actual service of the United States; he may require the opinion, in writing, of the principal officer in each of the executive departments, upon any subject relating to the duties of their respective offices, and he shall have power to grant reprieves and pardons for offenses against the United States, except in cases of impeachment.
"He shall have power, by and with the advice and consent of the Senate, to make treaties, provided two thirds of the Senators present concur; and he shall nominate, and by and with the advice and consent of the Senate, shall appoint ambassadors, other public ministers and consuls, judges of the Supreme Court, and all other officers of the United States, whose appointments are not herein otherwise provided for, and which shall be established by law: but the Congress may by law vest the appointment of such inferior officers, as they think proper, in the President alone, in the courts of law, or in the heads of departments.
“The President shall have power to fill up all vacancies that may happen during the recess of the Senate, by granting commissions which shall expire at the end of their next session.”
So there’s nothing in the Constitution which specifically imparts police power to the President. He has the power to make citizen’s arrests just like everyone else does, but he can’t IMHO directly order an arrest. But, be real, if the President of the United States says “arrest that man” is the Secret Service or any cop standing around not going to do it?