I’m following Roger Daltrey’s tour on the ‘net and I’ve been impressed by Katy Jacoby’s violin solo on Baba O’ Riley – originally laid down by Dave Arbus. Nobody in the band could’ve done that.
Clapton’s solo on While My Guitar is another instance of an iconic non-member solo. Harrison, Lennon or McCartney were good guitarists, but they didn’t have the chops to match what Eric did.
Elliott Randall’s lead guitar work on Steely Dan’s Reelin’ In The Years is one of my favorites of all time. When I bought the albumin 1972, I noticed a couple of things that struck me as weird. The band had a lead singer, David Palmer, who only sang lead on one or two songs, and they had two great guitarists, Jeff Baxter and Denny Dias, and used a guest guitarist on the most guitar-intensive song on the album.
All of this made more sense when it later became apparent that Steely Dan was really Becker and Fagen.
Although not technically a Mothers of Invention album, Apostrophe features much of their line-up, as well as Jack Bruce’s awesome bass solo on the song “Apostrophe”.
Al Kooper’s organ on Dylan’s “Like a Rolling Stone.” Dylan was not using an actual band, but Kooper was only in the studio to observe. He managed to sneak in and sit at the organ and made up his part as he went along.