She was in A View to a Kill and wasn’t really a Bond girl per se (Tanya Roberts was in that film) but an enemy femme fatale that he bangs.
Who was that blond guy that threw a motorcycle at Moore in “For Your Eyes Only”?
John Wyman. link
Richard Kiel, but only if he did the role in his To Serve Man makeup.
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(By the way, he actually wasn’t a bad-looking guy if you cleaned him up a little)
Like the OP said, Toby Stephens (the villain in Die Another Day) could do it - he’s already played Bond on radio.