Unless there are lots of kids and the pool is poorly maintained, your typical pool will have between 2 and 3 parts per million of total chlorine, the vast majority of which should be free available chlorine. If you have a ton of people or kids in the pool a lot, and the chemicals get neglected, you could have mostly combined chlorine, and I don’t know if I’d want to drink that.
As for chlorine dissipation, most pool owners now use tabs, which contain some cyanuric acid. While this is a good thing for pool owners, it’s not so good for people who want to drink the water, as it protects the chlorine from the UV rays, somewhat, so the chlorine will stick around a bit longer.
I’m not a chemist, even though as a pool owner I sometimes feel like one, but these are rough averages for some of the common attributes of a well balanced pool, so if anyone sees anything that would make it undrinkable, chime in:
Chemicals, in parts per million:
Chlorine: 2-3
Cyanuric acid: 40-50
Alkalinity: 120
Calcium hardness: 250
Most pools also have a ph of between 7.2 and 7.6 or so, which is definitely not a problem.
A couple of things to watch for, superchlorinating (what is sometimes called “shock”, although shock comes in non-chlorine forms as well, so I don’t use that term here), which is done to free up combined chlorine. In those cases, the chlorine level can easily reach 30 ppm or even higher. Also, when a pool gets too alkaline, pool owners pour in muriatic acid. While I’m sure that dilutes pretty quickly, you certainly want to wait many hours after an application, as that is some of the nastiest stuff around. Finally, without a test kit, it’s going to be really hard to tell whether the pool is well balanced, or deadly as hell, just by looking at it. There are many ways of achieving clear, sparkling water, some of which aren’t really conducive to making it safe for drinking.
There are a variety of other chemicals that are used for various purposes (sometimes simply because the pool supplier said it was needed), but the above are the basics that you can expect in most pools.
I’ll let people who know about those things actually answer whether this all means that you can drink it or not.