Slow burning propellant and fast burning propellant are relative terms. They both burn within milliseconds of being ignited. The gas pressure expands at a relatively slow rate (zero to 700fps, zero to 4,000fps) until the projectile exits the barrel, at which point the gas (and unburned powder) will pass the bullet at over 5,000fps.
All rifle, pistol, revolver, shotgun manufacturers, custom barrel and action makers, and propellant manufacturers build their products to the Sporting Arms and Ammunition Manufacturers Institute (SAAMI) standards.
It’s assumed that cartridge built to SAAMI standards will fire safely in a rifle built to SAAMI standards.
My first thought at someone’s replacing modern smokeless propellant with HE would be to call my brother. He’s never seen a firearm explode.
But on a more serious note, if a small amount, certainly not one of equal mass, of HE were to be substituted for the usual brand, shape, and recommended weight of Wonderbang xxxx, it would have to closely match the pressure expansion rate, and burn time, of the recommended propellants.
Interior balistics (what happens inside the firearm) covers many steps. First, the primer has to be crushed and ignited. 2nd, the HE has to be ignited in a controlled, repeatable manner. 3rd, the gas pressure has to overcome the crimp holding the bullet. 4th, the gas pressure then has to overcome the swaging effect of the bullet entering the forcing cone. 5th, the pressure has to overcome the friction of the bullet’s bearing surface on the lands and grooves as it travels down the entire length of the barrel. The final step being the bullet poping free of the muzzle. Except for the last step, which decreases the gas pressure, each step impeads the free flow of the bullet, and increases the gas pressure.
If the gas pressure exceeds the design limits of the barrel, or the action, of the firearm before the bullet pops free, you’re gonna shoot your eye out kid.
As an after thought, smokeless propellent is packed loosely, and unburned/soon-to-be-burned-powder is free to travel down the barrel behind the bullet. Isn’t HE a formed explosive? Would that make a difference in the burn rate? Would the gas pressure in the chamber area exceed design limits before the bullet exits the muzzle?