If you mean is there an area code that would always send you to directory assistance, then the answer is no for the UK (there are numerous directory assistance numbers but they’re all six digits beginning 118).
My impression from German TV shows and movies is that usually spelling out or displaying ficticious phone numbers is avoided - instead people hand over business cards or notes, or point to a number on a document etc. Ficticious area codes mostly have the disadvantage of obviously not fitting to the regional setting.
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Only 555-1212 sends you to directory assistance. 555 numbers work a lot like 800 numbers, and can be local or national (with just 7 digits). Number assignments are here http://www.nanpa.com/number_resource_info/555_numbers.html.
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If the second column is “N”, then yes, it is a national line. Just like 800 numbers, you can specify which area codes it is valid for, so even if it is listed as national, doesn’t mean that it can be reached from every area code. I think 555 numbers can be setup toll free, toll, or pay (i.e. 800-, regular, or 900-).
As for personal numbers, there were a lot of speculators that grabbed numbers when these became available about 10 years ago. A quick search turned up a friend who holds twenty 555- numbers. The vast majority of 555 numbers remain unimplemented.