There are scientists who have been described as great experimentalists. Mostly not physicists, because of the nature of physics, but there are some great experimental biologists and chemists.
These are people who, usually early in the development of their science, made brilliant insights into the results of their experiments that often ran ahead of current theory. Often they stumbled on some concept that their science couldn’t explain with its current knowledge, but which was later found to be correct.
Simply adhering to good experimental procedure (accurate measurements, thorough recording of results) is part of being a good scientist, but not enough to constitute an ‘experimental genius’. It’s the correct interpretation of their results and the far-reaching implications of them that makes great experimental scientists.
Mendel is the only biologist that really comes to mind, and even he is rumored to have ‘cooked’ his data. But That’s Not My Field.
Some chemists who are generally considered great experimenters:
Henry Cavendish, analyzed air in 1785 and found that a very small fraction (0.94%) was a gas he couldn’t identify. He considered this to be the probable result of experimental error, but he recorded the data anyway. In 1894, over 100 years later, Raleigh and Ramsay determined that Cavendish’s unidentifiable gas was argon. He also invented a torsional balance that was able to estimate the gravitational constant G (and the mass of the Earth).
Emil Fischer was able to deduce the correct structures of glucose and all the other known sugars, including their stereochemistry, using the primitive organic chemistry available to him in the early 1880s. His complex, multi-step process of breaking down, modifying and identifying glucose atom-by-atom was an absolutely brilliant piece of deductive reasoning as well as of organic chemistry. His experiment is still taught today, and the logic of it is still impressive even if the results he gleaned through years of work can now be obtained by an undergraduate in an hour.
Those are probably the classic examples, at least in chemistry. There are some synthetic organic chemists, even today, who have worked out paths to complex (> 50 carbon atoms) molecules from simple (~< 6 carbons) starting materials. Their logic can be complicated, but it is deeply insightful. (Corey and Woodward are the classical Brilliant Synthetic Chemists, if you want to look them up.)