I have designed oxygen systems for chemical plants where typically the oxygen is separated cryogenically to 96 - 99.5% and then pumped as a liquid to high pressure and finally vaporized to give high pressure oxygen.
It would have really helped if you mentioned the final pressure and the flow (do not understand if the LPM is at low pressure or higher pressure) you were looking for - since we do not have that, here are some considerations I would go into :
1> Buy a compressor rated for oxygen service. Look at the Oxygen booster compressors (if they meet your pressure/flow needs) at http://www.rixindustries.com/oxygencompressors.html
2> Since you are going to header a lot of Oxygen concentrators together, make sure you are using good check valves if there is a concern that you can have one concentrator flow into the other one. If possible - use the fewest concentrators. Also - keep in mind to have a good size manifold.
3> Look into the velocity and pressure and see if you can use exempt metals (again knowing the flow/pressure would have helped here). You can look at a good guide on oxygen piping here : http://www.eiga.eu/fileadmin/docs_pubs/Doc_13_12_Oxygen_Pipeline_and_Piping_Systems.pdf
4> Pay special attention to valve internals to make sure they do not react with Oxygen. Use large radius bends and fittings to avoid local areas of high velocity.
5> Understand cleaning for oxygen service - you need to remove all residues / paint etc - here is an industrial guide, hope you can use the concepts from it : http://www.asiaiga.org/docs/AIGA%20012_04_Cleaning%20of%20Equipment%20for%20Oxygen%20Service.pdf
6> Have a purge system - so you can purge out the system once you are done. If you are going to use compressed air - ensure there is no oil in the compressed air.
7> Look into cooling the oxygen (if needed) after the compressor. Look into providing a volume after the compressor. Understand how you will control flow from the oxygen concentrators - provide block valves , so you isolate individual oxygen concentrators.
8> Since you will have a lot of oxygen concentrators putting out a lot of N2 purge gas - make sure you are doing this in a well ventilated area otherwise the air you breathe may become deficient of Oxygen
I think you are taking the right approach of understanding the risks and mitigating them by good design. Oxygen deserves utmost request - and please understand the complete risks. The above are only some considerations - there are others that need to be understood and solved.
Oh I forgot - please use a flow meter rated for oxygen service or take a regular flow meter (check if the materials are suitable for O2) and calibrate it.