while getting my new Drivers license, I chose to be donor, but later I thought if this is realistic option. After death, how long are kidneys, liver, etc viable for transplant?
After death, not long. But you can be kept alive with a catastrophic brain injury for a long time while, that is the typical case for organ donation. So yes, please check off the organ donor box.
Valves are stripped of all of their living cells, leaving only the connective tissue behind. They are, effectively, turned into leather. They’ll last a good long time frozen.