Hardly any of the colors we see in the “real world” (i.e., outside of special laboratory setups) are pure single wavelengths (“monochomatic” light), even when they look like pure unmixed colors or seem indistinguishable from the sensation you get from pure light of a certain single wavelength. Many hues that we experience cannot be found in the spectrum (i.e., cannot be produced by any unmixed wavelength of light), but are only produced by certain mixtures of wavelengths. Indeed, IIRC,* the color that most people judge to be the best, most pure and unmixed looking red, cannot be produced by any single wavelength of light. Any reddish monochromatic wavelength that you choose is going to look either a little bit orangey or a little bit purplish to most people. Subjectively “true” red can only be produced by a mixture of wavelengths.
On the other hand, certain colors that are subjectively indistinguishable to the human eye can be produced in more than one way, by mixing different wavelengths in different proportions. These are known as metameric colors: i.e., two quite different mixtures of wavelengths that produce the same subjective effect, are metamers of one another.
Furthermore, some colors that we routinely experience cannot be made merely by mixing wavelengths of light in any way whatsoever. So called “contrast colors” are only experience when a surface with one pattern of spectral reflectivity is adjacent to a surface with a certain range of other spectral reflectivity. Brown is a good example. You cannot make brown light by mixing together any wavelengths of light in any proportions. Furthermore, you cannot fill your entire visual field with brown. The nearest you will be able to get is some sort of orangey or yellowish color. However, if you place something of the appropriate orangey or yellowish spectral reflectance adjacent certain other colors (generally lighter ones), it will appear brown. Of course, in real life our visual field is almost never filled with only one spectral mixture, so in practice, brown can, and does, appear quite frequently. (I stumped more than one of my high school physics teachers, trying to teach us about the spectrum, by asking them where brown comes from. I did not find out the real answer until several decades later.)
All in all, the eye is not a spectral analyzer, and the colors that we see and can distinguish between are only related in a very indirect and complex way to the actual spectral reflectances of objects. Presumably, the color distinctions we can make are those that were adaptively useful to our ancestors (it is very useful for many monkeys, for instance, to be able to distinguish between ripe and unripe fruit, and between unripe fruit and leaves), plus others that we got for free along with the mechanisms that were selected for making the useful distinctions.
*My uncertainty here is over whether this applies to red, as opposed to one or other of the other so-called "primary" colors. I think it is red, but it might possibly be subjectively pure green or blue (or perhaps even all of them, or two out of the three) that corresponds to no monochromatic wavelength. If anyone knows about this, and can provide a cite, I would be grateful.
[quote="CookingWithGas, post:1, topic:543231"]
With sound, we perceive two tones (sufficiently close together) as a single tone that is the average of the two frequencies
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This does not sound right to me, but I am not certain. Does anyone know better, or have a cite?