From http://www.straightdope.com/columns/010105.html
I pondered this bleakly for a while. Then a thought occurred to me. Al, I said, the highest you can raise water in a siphon is around 34 feet. By curious coincidence, the maximum height that water can be drawn in a tube sealed at the top (a water barometer) is also around 34 feet.
With sincere respect to your work Cecil (and I’m a long time fan), I agree with Uncle Al, the tensile strength of the liquid is what keeps the fluid together provided the vapor pressure of the liquid is less than the ambient pressure.
The 34 feet limit is no coincidence, and it isn’t constant. Cavitation (a.k.a. boiling in pure fluid systems) occurs when the vapor pressure of the liquid (a thermodynamic property of the substance) equals the ambient pressure. The water vapor pressure is related to the temperature. At room temperature (25 C), the water vapor pressure is 3.166 kilopascals (ref 1 below), while atmospheric pressure is 101.3 kPa. The pressure differential is 98.1 kPa, giving plenty of room for a negative suction pressure.
If you apply the familiar hydrostatic pressure equation, dP = rhog/gch, where dP is the pressure differential, g is gravitational acceleration, rho is the density of water (1000 kg/m3), gc is the conversion constant from mass to force in Newton’s second law, h is the height, you see that (98,100 N/m2)/(1000 kg/m3)/(9.81 m/s2)*(1.0 kg m/N s2) = 10 meters, or 32.8 feet.
When you go higher than that in a barometer (meaning you draw water up a tube with suction), the pressure at the top of the fluid column is near 3.1 kPa and the water boils. Increase the temperature of the water to 80 deg C, making the vapor pressure 47.34 kPa, dP is 53 kPa, and the height is 18 feet. These calcs are for pure water, gases and such affect the vapor pressure, but have only an indirect influence on siphoning.
Now, let’s assume you have two expandable bladders with no air, each filled to half capacity connected with a filled tube at equal elevation. Drop the elevation of one below the other, and all the water in the top one will go to the lower bladder without the influence of the atmosphere. There would be no driving force from the bladders themselves, no atmosphere, indicating gravity is pulling the water to a lower energy state. The water remains liquid because thermodynamics says it’s phase remains liquid at those conditions.
I was about to discuss the capillary action argument brought up by Al, and then after some homework decided he knew what he was talking about, which often seems to be the case when talking science with “Uncle Al.”
I hope this helps, all comments and criticism gladly welcomed.
Regards,
Dr. Dennis Hussey
Research Engineer
Chemical Engineering
Oklahoma State University
- Smith and Van Ness, Introduction to Chemical Engineering Thermodynamics, Appendix C Steam Tables.