K2-18 is the whole star system. K2-18-a is just the star; the primary subcomponent of the system.
“If the parent star is a single star, then it may still be regarded as having an “A” designation, though the “A” is not normally written. The first exoplanet found to be orbiting such a star could then be regarded as a secondary subcomponent that should be given the suffix “Ab”. For example, 51 Peg Aa is the host star in the system 51 Peg; and the first exoplanet is then 51 Peg Ab. Because most exoplanets are in single-star systems, the implicit “A” designation was simply dropped, leaving the exoplanet name with the lower-case letter only: 51 Peg b.”