It’s like comparing the English and Metric systems. If you grow up in one, then all its quirks and inefficiencies are second nature but adapting to it as an adult is painful.
Both LoC and Dewey have massive problems with consistency. They just manifest differently. Take something as simple as fiction. You’ll find fiction in the PS classification, although the official classification might give you pause:
If you go to the shelves, you’ll notice that within those numbers, the alphabetical sequence reboots periodically, so books by the same author over time might not be next to one another. And heaven forfend that a writer turns to science fiction, because that might be classified as PZ:
Wait, what? Fiction in English is different than prose fiction? Sure, if it’s that slimy genre stuff. PZ is also where “juvenile belles lettres” are stored, so the connection in their minds, if nobody else’s, is obvious.
Don’t bother trying to figure out where anthologies and single author collections might be sitting. You can’t do it without a scorecard.
This general confusion extends into every sub-branch of nonfiction as well. Any research inquiry into any subject will take you walking through miles of shelves looking for books under different starting letters.
The reason is identical to the problems with DD. No two books are exactly alike. The classifiers don’t actually read every book that comes through their hands. They go by general information provided by the publisher. A shade of emphasis can get a book placed into a different category. Time plays a huge role. As a subject grows it reveals meanings, associations, and connections not previously thought of. And sometimes shifts are made for no apparent reason at all to an outside. Humor once was in 817, then got moved to 814 and now sits at 814.54. Unless it’s at 818 and 818.54. An author with a long career, like Dave Barry, is guaranteed not to have his books together.
And don’t get me started on their habit of giving the paperback reprint a different number from the original hardback. That’s incomprehensible.
But as long as human beings and their subjective understandings are involved, this is inherent in any possible classification system. All that matters is your familiarity with it or conversely your willingness to start each search fresh from the catalog and forget everything that you’ve painfully learned.