Why isn't Yttrium considered a Rare Earth? Or can it be?

  1. Ce-Lu form the inner transition series, each with 2-14 electrons in the 4f block.

  2. La + Ce-Lu are collectively called the “Rare Earth Elements” because of their similarities, even though La doesn’t have f-electrons, instead having an outter-shell electron configuration of 5d1 6s2.

  3. Y has the same outter shell configuration as La: 4d1 5s2.
    Additionally, it has the same size and charge as the HREE (esp. Ho) and “behaves” similarly in geochemical systems.

So, why isn’t Y generally considered to be a REE? Or is it? Or is it not, but can be?

according to Cotton and Wilkinson “advanced inorganic chemistry” Yttrium can be considered a rare earth metal

Im pretty sure it is considered rare earth - er thats how i knew it anyhow

-PK

I’m not a chemist… but I’ve read Isaac Asimov’s essays on the discovery of the rare earth metals (in his collectionThe Stars In Their Courses), where he includes yttrium (and its neighbours scandium and lutetium) in the category.

I think there may be a distinction of terminology here, though; scandium, yttrium and lutetium may be rare earths, but they’re group 3 elements, not part of the lanthanoid transition series which includes all the other rare earths. So, there may be some tendency among chemists - heck, for all I know, it could be official nomenclature - to say “rare earth=lanthanoid”.

(Obligatory reference link to WebElements)

Some Cites:
Chemicalelements.com does not list yttrium as a REE.

http://www.esu1.k12.ne.us/~lweb/Lakeview/science/y.htm:

http://www.iversonsoftware.com/reference/chemistry/r/Rare%20Earth%20Elements.htm

http://www.pir.sa.gov.au/pages/minerals/resources/commodity/rare_earths.htm:sectID=245&tempID=7