While I was in high school, I encountered someone selling a product like this at a county fair. I read through a binder full of strange ‘scientific’ reasons why this improbable-looking device would work. I didn’t say anything, but I remember many of these same arguments being used. None of them make much sense at all.
This is a paragraph-by-paragraph analysis of the page at the link provided above.
Hydrogen atoms as a basic element of fuel
The author seems rather unfamiliar with the concept of atoms and molecules. Hydrocarbon fuels are made of hydrogen and carbon atoms bonded to each other in specific patterns. (The next paragraph suggests that the author thinks the hydrogen atoms are free.) The use of the terms ‘K shell’ and ‘L shell’ suggests an outdated knowledge of chemistry; these terms are still used, but it is more common to refer to ‘energy levels’.
Hydrogen atoms and ‘free electrons’
An electron which is not paired with another in its orbital is generally known as an ‘unpaired’ electron, not a ‘free’ electron. In a hydrocarbon, hydrogen atoms are invariably bonded to carbon. Each hydrogen atom ‘shares’ its electron with a carbon atom, and the carbon atom in turn ‘shares’ one of its electrons with a carbon atom. This is known in basic chemistry as a ‘covalent bond’.
Increasing the energy of a free electron, making chemical reasons more efficient
It’s possible to make an electron in a molecule transfer from one energy level to a higher energy level, which is called ‘exciting’ it. This requires a specific amount of energy. For most of these possible transitions, the energy required is in the ultraviolet range, though some electrons can be excited by visible light. Various things can happen when an electron is excited; most involve the emission of light. Sometimes a bond can be broken to form a different molecule, or an electron can be removed from the molecule, forming a reactive ‘free radical’. Radicals are important in combustion, and there are legitimate ways of improving the efficiency of an engine by introducing radicals. (Tetraethyllead in leaded gasoline is a source of radicals.) However, you can’t make radicals with a magnet.
The analogy with photosynthesis
This is an entirely incorrect analogy. It’s true that photosynthesis involves the promotion of electrons in atoms by light. Specific wavelengths of light are required for this. Light, not permanent magnets.
Boosting the efficiency of the fuel
A magnet is not an effective energy source. It certainly does not provide energy of the wavelength required to do what it claims, to promote electrons in hydrogen atoms to higher energy levels. Also, modern engines burn most of their fuel (once the engine has warmed up) completely to carbon dioxide. There isn’t much room to increase fuel efficiency by encouraging more complete combustion. It’s true that adding radicals to the fuel mixture will improve the engine’s performance, but radicals aren’t formed by magnets. Even if it did, radicals are highly reactive and most are short-lived. It’s doubtful that free radicals formed in the fuel line would last long enough to affect combustion in the engine.
More efficient combustion
I don’t really know enough about engines to handle each claim made in this section. First, magnets won’t form radicals. Second, the amount of chemical energy available in the fuel is fixed and can’t be increased provided that all the fuel is burned in the engine. A modern, well-tuned engine should burn all the fuel it receives, and should produce very little CO. It’s possible that adding radicals to the fuel might make the engine slightly more efficient by making more of the fuel combust completely to CO[sub]2[/sub], but there are more practical ways of doing this. Also, providing the engine with a fuel that is different than the fuel it was designed for might make the engine less efficient. Different types of engines have different types of combustion. Gasoline and diesel engines, for example, work differently, and a modification to the fuel that makes a gasoline engine work better may well make a diesel engine perform more poorly.
Crystal structure of carbon
This seems to be a way of accounting for how the device affects the other ‘basic element of fuel’, carbon. It seems to neglect the fact that carbon and hydrogen atoms in fuels are bonded to each other. Fuels are not mixtures of hydrogen and carbon atoms. Also, fuels are liquids, and do not have a crystal structure. Heat and pressure will change the ‘crystallization’ of pure, solid carbon. But a magnet cannot possibly change the crystal structure of a fuel, because it does not have one.
van der Waals forces
The statement that “hydrogen forms cage-like structures which … form pseudo-compounds [when combined with carbon]” may explain much of the faulty reasoning here. The author seems to believe that fuels are a loose association between hydrogen atoms (presumably in ‘cage-like structures’) and carbon atoms. This is, at best, an obsolete understanding of structure in organic molecules. The sidebar seems to provide a second explanation of the device. I’m not sure whether it’s supposed to be an explanation of how the ‘free electrons’ are promoted, or if it’s trying to say that the device makes oxygen bind with fuel better, or that it aligns the fuel in a certain magical way. In reality, van der Waals forces are weak attractions between temporary electric charges (induced dipoles). They are not, AFAIK, affected by magnetic fields. (I’m basing this on the fact that van der Waals-related parameters are not substantially modified in NMR spectroscopy, which involves a magnetic field far stronger than an ordinary permanent magnet.)
So, I do not think this device can work in the manner that it claims. I can’t explain the test results, however. (Note that this does not mean that the test results are necessarily valid, or can’t be explained. Perhaps the engines were tuned up, or some other parameter was changed that made the engines perform differently.)