Decompression illness (the bends) arises when inert gases dissolved in the body tissues are brought out of solution by a decrease in ambient pressure. When a diver descends (or a deep mine worker, for that matter), the atmospheric pressure increases, correspondingly increasing the partial pressures of the component gases in the breathing media. When breathing air, the sea level partial pressures are 0.791 ATA for nitrogen, and 0.209 ATA for oxygen. These same partial pressures exist in the body tissues under the same conditions, and everything is in equilibrium. Upon descent, the partial pressure of both gases in the surrounding air is suddenly higher than that dissolved in the body tissues, so “ongassing” begins, and the level of these gases dissolved in the tissues increases accordingly. This is a rate limited process, however. Different tissues ongas and offgas at different rates, and also exhibit different degrees of inert gas solubility within them. For example, this happens quite quickly in blood, slowly in bone marrow, a lot of gas is dissolved in fatty tissue, not so much in lean muscle, etc. Saturation (equilibrium) is only achieved when enough time has passed at depth to allow all of the tissues to come to equilibrium. The bends, caisson disease, and decompression sickness are all the same thing. As you ascend, the tissues become supersaturated (or at least one or more does - the slowest ones may still be trying to catch up if you are not yet fully saturated) with this dissolved gas as the ambient pressure lessens, and the gas comes out of solution into bubble form. Oxygen, thankfully, is metabolized, and we usually don’t need to worry about oxygen bends. Inert gases such as the nitrogen in the air, or helium (often used when deep diving) need to be eliminated. Ordinarily this is done as the bubbles enter the bloodstream and are removed by the lungs (exchanged through respiration). Unfortunately, this only works effectively if the bubbles are below a certain critical size, and if the rate of offgassing is slow enough for the lung filter to keep up. This is why divers employ decompression stops - the deco time allows the physiological processes to come closer to equilibrium at the stop depth before proceeding, keeping the amount of supersaturation of gases within the body tissues within tolerable limits.
In your tube-through-the-earth example, the air in the tube, under the influence of gravity, will be at a higher pressure than the surface air. I don’t know how to calculate that pressure (perhaps an atmospheric science buff could step in here?), but the only way you could get “the bends” in this scenario is if the rate of ascent (and hence, decrease in ambient pressure) was great enough that the tolerable dissolved gas supersaturation in one or more body tissues was exceeded. This necessarily implies that either the pressure was great enough, or the exposure time great enough (so rate of fall is a factor) to create that level of saturation prior to passing the center and rising to a height high enough that tolerable supersaturation is exceeded.
If you are falling in air, you are going to reach a terminal velocity beyond which you will not accelerate (apart from variances in the fall rate due to your size and shape, and your body position while falling). Density of the air also plays a role, and in fact your speed will decrease as you encounter denser air
-WHOOPS- it just occurred to me that air, under the influence of gravity, will behave according to that influence, and since gravity is a function of distribution of mass, it actually decreases as you approach the center of the earth, where you would, in effect, experience weightlessness. What this means for the air pressure I’m not sure, since the pressure is dependent on the weight of the column of air above any particular point - I guess all that implies is that the rate of pressure increase will not be precisely linear with depth - whatever, I digress…
The point is that you quite likely wouldn’t be doing much more than 200 mph as you pass the center, and would then come to a halt a ways beyond that, as gravity pulled you back in, and you would oscillate back and forth across the center point until drag brought you to a stop at dead center. Also, the effect of ambient pressure change on the bubble size is proportional to absolute pressure. Closer to sea level, a given change in depth will result in a greater change in bubble size than if you changed depth by the same amount at a deeper depth. As a diver, you can ascend faster while deeper, but must slow the rate down as you approach the surface. Consequently, I wouldn’t expect the overshoot as you fly past the center of the earth to be significant, but than it depends on the absolute pressure, which as I already admitted I don’t know how to calculate for air.
Clear as mud?