It’d be different for every household.
I bet most get chunks of time to themselves every day, with the occasional emergency call.
Alice probably worked from 6:30-9, then from 11:30-2, then from 5:30-8, or something like that, with the in-between times being her own. Remember, she had time to date the Sam the Butcher.
She probably had to do once-a-week things too, like shopping, mopping, vaccuming, certain laundry loads, etc. those might get done between her split shifts on certain days.