Last letter = First Letter, min 3 syllable word chain

axiomatic

cerulean

navigational

libration

Nosferatu

understandable

estimated

dirigible

ecdysiast

tachometer

radiological

lampoonery

yamaha

Allamagoosalum

monstrousness

strangulation

nanosecond

dithyramb

boomerang

geothermal