Last letter = First Letter, min 3 syllable word chain

delusional

lullaby

Yugoslavian

-“BB”-

niggardly

Yarrowford

deshabille / dishabille (I understand either spelling is acceptable)

-“BB”-

epitaph

hieroglyphic

cuneiform

mummification

necrosis

-“BB”-

spaghetti

Intermittent

tyrannical

langoustine

extremism

mesothelioma

-“BB”-

accounting

generic

concupiscence

-“BB”-