Last letter = First Letter, min 3 syllable word chain

laminated

delineated

demolish

-“BB”-

haruspex

xenomorphic

consternate

embodiment

telepathist

tectonic

cacanapa

aperitif

fisticuff

Falstaffian

ninety-eight

tarantula

Aragorn

ninety-six

xanthophobia

fear of the color yellow

albatross!

seagoing