Last letter = First Letter, min 3 syllable word chain

temtation

neufchatel

Lorenzo

oenology

yachtsmanship

pteranodon

nomenclature

ecdysiast

temptation

nattiest

tintinnabulation

Narcissus

shadowbox

xenophobic

conflagration

-“BB”-

nursery

Yeatsian

notarized

document

terrifying