Last letter = First Letter, min 3 syllable word chain

emasculate

effortless

satisfying

Gatlinburg

gematria

alliterative

Everclear

rudimentary

-“BB”-

Yakkity-yak

kleptomaniac

chrysanthemum

Metropolitan

nomenclature

enthusiastically

Yarborough

holistic

Californian

nomenclature

electrical

latitude