Last letter = First Letter, min 3 syllable word chain

double-deckered

dilapidated

Definitely

Yuzovka

angioplasty

Yokohama

adventurers

Scarlatti

ironic

catapult

theocratic

crazymaking

gaslighting

geodesic

catastrophic

chumbawamba

atypical

-“BB”-

logistical

Logansport

tangential