Last letter = First Letter, min 3 syllable word chain

liquified

diphtheria

-“BB”-

atmospherical

lollipop

parallax

xenial

lapidarist

Thalassa

alpaca

artichoke

eighty-third

dramatic

castigate

-“BB”-

eradicate

expatiating

gurgitate

Expiation

necrophilia

abacus

sensationalistic