Last letter = First Letter, min 3 syllable word chain

sacramentarianism

multiplication

Nebuchadnezzar

rhinoplasty

ypsiloid

damoiseau

unmentionables

squamulose

eschatology

yummier

realism

mucago

orbicular

reticulated

dinosaur

rixatrix

xanthocomic

chasuble

excommunicated

dalmatic