Last letter = First Letter, min 3 syllable word chain

elliptical

lambrequin

neocatastrophism

mistaken

nasopharyngeal

leavening

gargantuan

nephrology

yuppiedum

mysterious

speculatrix

xenophobically

yeomanette

encyclopedic

cephalonomancy

Yakitori

inclement

toxicology

yeomanry

yogibogeybox