Last letter = First Letter, min 3 syllable word chain

simplistic

curmudgeon

nomenclature

Etruscan

Nutella

Andromeda

architectural

languorous

Sacagawea

aptitude

Edgerton

Norepinephrine

epiglottis

stegosaurus

syphilitic

catastrophe

ellipses

sacroiliac

(SS) Californian

N’Jadaka