Last letter = First Letter, min 3 syllable word chain

netherworlder

redemption

navigational

latitude

eskipoo

A ‘designer dog’ breed achieved by crossing an American Eskimo dog (which was formerly known as the ‘Spitz’ until being renamed because of anti-German sentiment during WWI) and a poodle.

-“BB”-

ontological

lariat

Tucumcari

impossible

electrocution

notwithstanding

groundbreaking

Goliath

hegemonic

coincidentally

Yugoslavia

arduous

salacious

symbolism

management