Last letter = First Letter, min 3 syllable word chain

[knoodler]

Romanov

[burpo_the_wonder_mutt]

voltaic

[llikewise]

catalytic

[knoodler]

circumstance

[llikewise]

ecumenical

[knoodler]

lolicon

[burpo_the_wonder_mutt]

Northwestern

[Prof.Pepperwinkle]

nocturnal

[Cardigan]

lachrymose

[llikewise]

eucalyptus

[Spiderman]

ahem, Spiderman (is my submission unless you don’t allow proper nouns)

[Prof.Pepperwinkle]

ne’er-do-well

[burpo_the_wonder_mutt]

Lithuanian

[knoodler]

numerologist

[llikewise]

tarantula

[Elendil_s_Heir]

adventurous

(Yes, we allow proper nouns, Spiderman).

[knoodler]

submarine

[Prof.Pepperwinkle]

Erato

[Cardigan]

occupation

[burpo_the_wonder_mutt]

newspaper