Last letter = First Letter, min 3 syllable word chain

glissando

ornithopter

-“BB”-

radiant

Transylvania

approximately

yellowing

Gastrocnemius

sensational

larcenous

serendipitous

sesquipedalian

necromancer

religion

-“BB”-

nihilism

misaligned

dependent

transcontinental

lifesaver

revanchist

tangential