Last letter = First Letter, min 3 syllable word chain

naturalization

nightmarish

hagiographic

Corporately

youthfulness

Stereotypical

laconic

Candelabra

Astyanax

One of the most pathetic characters in the story of the fall of Troy.

xesturgy

the process of polishing

yesteryear

Recidivism

melatonin

nativism

metabolism

Melancholy

Yreka

anteater

Righteousness

schadenfreude