Last letter = First Letter, min 3 syllable word chain

nectarine

Encapsulated

devilish

habitual

lollipop

Papua

quiescently

Wrong thread? Been there, done that.

Playing off “Papua”:

absolution

negotiation

numerical

Libertarian.

nobility

yammering

gingivitis

supernatural

Beats the hell out of me, Roy.

libelous

Serengeti

idiotic

championship

prescription