Last letter = First Letter, min 3 syllable word chain

Estonia

Apalachicola

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technocrat

torrential

litany

Yolanda

anaphora

amnesiac

chimerae

exceptional

ludicrous

sacramental

Labubu

umbrella

aggravated

Ninja’d, never mind

laboratoral

Working off of aggravated:

Dominatrix

xenophobia