Last letter = First Letter, min 3 syllable word chain

Replica

apparatus

Syllabus

sarsaparilla

amazing

gallivanted

dependent

tomorrow

whatever

-“BB”-

rutabaga

arsenal

Lydian

national

Lithuania

alembic

catachresis
originally defined as ‘a semantic misuse of a word or phrase’, the word has since been used to describe figures of speech in which a word or phrase is being applied in a way that significantly departs from conventional (or traditional) usage

-“BB”-

synecdoche

existential

lariat

telegraph