Last letter = First Letter, min 3 syllable word chain

dandified

Disraeli

impresario

origami

ipiti

Islamabad

ichthyoacanthotoxism

Margaritaville

elucidation

nanosecond

discombobulate

elocutionist

tetrakishexahedron

northeastern

novella

Andromeda

antediluvian

nephelococcygia

arbalest

thermoluminescence